Research Article
A New Optical Sensor for Selective Monitoring of Nickel Ion Based on A Hydrazone Derivative Immobilized on the Triacetyl Cellulose Membrane
Kamal Alizadeh* and Nasim Abbasi Rad
Department of Chemistry, Lorestan University, Khorramabad, Iran
- Corresponding Author:
- Kamal Alizadeh
Department of Chemistry, Lorestan
University, Khorramabad, Iran
Tel: +986633120612;
Fax: +986633120612
E-mail: Alizadehkam@yahoo.com (or) Alizadeh.k@lu.ac.ir
Received date: May 24, 2016; Accepted date: June 10, 2016; Published date: June 17, 2016
Citation: Alizadeh K, Rad NA (2016) A New Optical Sensor for Selective Monitoring of Nickel Ion Based on A Hydrazone Derivative Immobilized on the Triacetyl Cellulose Membrane. J Anal Bioanal Tech 7:322. doi:10.4172/2155-9872.1000322
Copyright: © 2016 Alizadeh K, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
Abstract
A new highly selective optical sensor was prepared by de-esterification of triacetyl cellulose transparent film and chemical immobilization of 1-acenaphthoquinone 1-thiosemicarbazone (L) on it. The absorbance variation of immobilized 1-acenaphthoquinone 1-thiosemicarbazone on hydrolyzed cellulose acetate film of upon addition of 1.5 × 10-5 mol L-1 aqueous solutions of Zn2+, Pb2+, K+, Cu2+, Ag+, Ni2 , Cd2+, Ca2+, CrO4 2-, Hg2+, Co2+, Mn2+, Cr3+, S2 O3 2-, Mg2+, Na+, Al3+, Tl+ and Fe3+ indicated a substantiality much larger variation for the Nickel ion in compare to other studied ions. Consequently, the new hydrazone derivative L possesses a high selectivity towards this metal ion. Influences of various experimental parameters on Ni2+ sensing, including the reaction time, the solution pH and the concentration of reagents were studied. A linear relationship was observed between the variance in membrane absorbance(â脙聜脣聠脙聜芒聙聽A) at 337 nm and Ni2+ concentrations in a range from 5.01 × 10-10 to 2.04 × 10-5 mol L-1 with a detection limit (3σ) of 1.00 × 10-10 mol L-1. No significant interference from 100 times concentrations of a number of potentially interfering ions was detected for the nickel ion determination. The sensor showed a good durability and short response time with no evidence of reagent leaching. The optical sensor was successfully applied to the determination of nickel in real water samples.
